You can safely tame one from the back of a scorpion as I have not yet encountered any creature that will agro on the scorpion unless you attack. These things are still creepy af though. (This has only been tested on mobile)
Easiest and safest way to tame this is to lure it under water. They stop aggro and you can tame as you please. Just make sure you come up for air every once in a while. Also be sure the water is deep enough.
Full Ghillisuit, bug repellent, and balls of steel because these are scary to tame! They have the taming slot right behind their head about where the saddle would normally sit. Must approach from behind and only approach when feeding, stay away otherwise