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While Shadowmanes are not immune to the Purlovian dismount, if the Purlovia is hit at all during is dismount attack, the attack will be interrupted.

This includes damage from the shadowmane's thorns, and because the Purlovia does damage to creatures in between it and its target, if the Purlovia tries to dismount you, it will damage to the shadowmane, triggering thorns, and stopping the dismount attack.

Every now and then the Purlovia manages to sneak one through but is fairly rare.

Shadowmanes are also not immune to radiation, but with 30k HP who needs radiation immune tames?

More Purlovia Encountering Tips