If you are having issues with cannon ball shots registering torpor, wait to shoot it until right after the golem finishes an attack animation. I find that you can normally get 2 cannon shots in between each golem attack animation if you are quick.
It's a bit silly that kibble tames it a lot better than rocks or sulfur because even in the dossier it says that it lives off of absorbing nearby rocks and minerals. So mabey they should make it so you have to feed them a rare mineral like obsidian what if they made it so you could tame one fast and with high effectiveness by giving one a few hundred or few thousand obsidian . or what if there kibble was made out of a combination of ores and minerals .