Bola it, shoot it in the head with tranq darts, feed it spoiled meat! A very effective and easy tame. Be careful though, they're hard to see in grassy areas. I was taming a sabertooth once when it came up out of nowhere, I went unconscious before I could even run away. It took me 5 tries to get my stuff back from my dead body because the scorpian was always there. In the end, surpinsgly, my sabertooth survived the taming process and I ended up taming the scorpian right after!